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Nature Energy

Oxygen-tolerant electrochemical CO<sub>2</sub> separation using N-heterocyclic imines with superstoichiometric release per electron

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Nature Energy, Published online: 04 May 2026; doi:10.1038/s41560-026-02055-0 Electrochemically mediated CO2 capture typically makes use of sorbents that must be reduced before binding CO2, a process often hampered by competitive oxygen reduction reactions. Here the authors develop N-heterocyclic imines that capture CO2 in the neutral state and release it with near-theoretical Faradaic efficiency upon electro-oxidation, avoiding the competing reaction.

Nature Energy, Published online: 04 May 2026;

doi:10.1038/s41560-026-02055-0

Electrochemically mediated CO2 capture typically makes use of sorbents that must be reduced before binding CO2, a process often hampered by competitive oxygen reduction reactions. Here the authors develop N-heterocyclic imines that capture CO2 in the neutral state and release it with near-theoretical Faradaic efficiency upon electro-oxidation, avoiding the competing reaction.

— Source: Nature Energy (https://www.nature.com/articles/s41560-026-02055-0)

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